“Biochar Supported Nanoscale Iron Particles for the Efficient Removal of Methyl Orange Dye in Aqueous Solutions.” PLOS One, July 23, 2015. http://dx.doi.org/10.1371/journal.pone.0132067.
Abstract: The presence of organic contaminants in industrial effluents is an environmental concern of increasing global importance. One innovative technology for treating contaminated industrial effluents is nanoscale zero-valent iron supported on biochar (nZVI/BC). Based on Transmission Electron Microscopy, X-Ray Diffraction, and Brunauer-Emmett-Teller characterizations, the nZVI was well dispersed on the biochar and aggregation was dramatically reduced. Methyl orange (MO) served as the representative organic contaminant for verifying the effectiveness of the composite. Using decolorization efficiency as an indicator of treatment effectiveness, increasing doses of nZVI/BC yielded progressively better results with 98.51% of MO decolorized by 0.6 g/L of composite at an nZVI/BC mass ratio of 1:5. The superior decolorization efficiency of the nZVI/BC was attributed to the increase in the dispersion and reactivity of nZVI while biochar increasing the contact area with contaminant and the adsorption of composites. Additionally, the buffering function of acid-washed biochar could be in favor of maintaining the reactivity of nZVI. Furthermore, the aging nZVI/BC for 30 day was able to maintain the removal efficiency indicating that the oxidation of nZVI may be delayed in the presence of biochar. Therefore, the composite of nZVI/BC could represent an effective functional material for treating wastewater containing organic dyes in the future.
“Sorption of arsenate onto magnetic iron-manganese (Fe-Mn) biochar composites.” RSC Advances Accepted 28 Jul 2015. http://dx.doi.org/10.1039/C5RA12137J.
Abstract: Bimetal adsorbents attract much attention because of their good sorption ability to arsenate (As(V)). In this work, biochar-supported bimetal adsorbents were prepared through either direct pyrolysis of Fe and Mn ions treated pinewood biomass (FMM) or co-precipitation of Fe and Mn ions onto pinewood biochar (FMB). The two Fe-Mn biochar composites were characterized using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and energy-dispersive X-ray (EDS) analyses. Characterization results suggest that maghemite (γ-Fe2O3) and manganosite (MnO) are dominant metal crystals in FMM, while manganese ferrite (MnFe2O4) is the dominant bimetal crystal in FMB. Batch sorption experiments showed that maximal As(V) sorption of FMB and FMM were 3.44 and 0.50 g kg-1 respectively, which were higher than that of the unmodified biochar. As(V) sorption by FMM and FMB decreased with increasing solution pH (between 3-9). Results of this work suggest that co-precipitation is more effective in preparing magnetic Fe-Mn biochar composites for As(V) removal.
“The effect of paper sludge and biochar addition on brown peat and coir based growing media properties.” Scientia Horticulturae 193, 225–230. http://dx.doi.org/10.1016/j.scienta.2015.07.032.
Abstract: Peatlands are crucial sinks for carbon in the terrestrial ecosystem, but they are jeopardized by their use as fuel or as growing media. Much research has been performed aiming to find high quality and low cost substrates from different organic wastes, such as coir, compost, sewage or paper sludges, and thus decrease peat consumption. The main objective of this work is to study the effect on peat and coir-based growing media of deinking sludge (R) and biochar obtained by pyrolysis of deinking sludge at 300 °C (B300). For this reason, mixtures of peat or coir with deinking sludge and corresponding biochar were prepared mixing them at 50/50 v/v ratios. The results showed that it is possible to improve the chemical and hydrophysical properties of peat and coir with addition of biochar and deinking sludge. Indeed, biochar increased air space, water holding capacity and total porosity of peat-based growing media whereas for coir, the best hydrophysical properties were obtained after deinking sludge addition. Finally, the use of biochar plus peat as growing media can increase lettuce yield by more than 100% with respect to peat growing media, which can be related with the improvement of hydrophysical growing media properties. This yield increment along with the reduction of the over-exploitation of peat can justify the use of biochar as growing media in spite of the cost associated to the pyrolysis process.